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Hyperspectral imaging (HSI) technology has been increasingly used in Earth and planetary sciences. This imaging technique has been successfully tested on ice cores using VNIR (visible and near-infrared, 380-1000 nm) (Garzonio et al., 2018) and near-infrared (900 - 1700 nm) (McDowell et al, 2023)  line-scan cameras. Results show that  HSI data greatly expand ice core line-scan imaging capabilities, previously used with gray or RGB cameras (see summary in Dey et al., 2023). Combinations of selected HSI bands from the hyperspectral data cube improve feature detection in ice core stratigraphy, and map distribution of volcanic material, dust, air bubbles, fractures, and ice crystals in ice cores. Captured spectral information provides unique fingerprints for specific materials present in ice cores. This method helps to guide ice core sampling because it provides non-destructive, rapid visualization of microstructural properties, layering, bubble contents, increases in dust, or presence of  tephra material. Precise identification of these atmospheric components  is important for understanding past climate drivers reconstructed from ice cores. As part of the COLDEX project (Brook et al., this meeting) we adapted the SPECIM SisuSCS HSI system for ice core imaging. The ice core scanning system is housed inside the ca. -20ºC main NSF ICF freezer, and externally computer-controlled. The operator monitors scanning operations and communicates with personnel inside of the freezer via radio.  The system is equipped with a SPECIM FX10 camera that measures up to 224 bands in the VNIR range. We modified the ice core holder tray and installed a heated enclosure for the camera. The system uses SCHOTT DCR III Fiber Optic light sources with an OSL2BIR bulb from Thorlabs. IR filters are removed to extend the light spectral range beyond the 700 nm limit without heating the ice core surface during rapid (<5 minutes) scanning of an entire meter-long section. Emitted light enters ice at a 45º angle from two top and two bottom light sources. To calibrate absolute reflectance we use three Spectralon panels with 100, 50 and 20% reflectance values with every scan as well as several secondary reflective standards and USAF targets for geometric corrections. We are developing Python-based open source data processing routines and currently comparing HSI data with existing ice core physical and chemical measurements. The goal is to fully integrate the ice core HSI system with ice core processing at the NSF ICF. Dey et al., 2023. Application of Visual Stratigraphy from Line-Scan Images to Constrain Chronology and Melt Features of a Firn Core from Coastal Antarctica. Journal of Glaciology 69(273): 179–90. https://doi.org/10.1017/jog.2022.59.Garzonio et al., 2018. A Novel Hyperspectral System for High Resolution Imaging of Ice Cores: Application to Light-Absorbing Impurities and Ice Structure. Cold Regions Science and Technology 155: 47–57. https://doi.org/10.1016/j.coldregions.2018.07.005.McDowell et al., 2023. A Cold Laboratory Hyperspectral Imaging System to Map Grain Size and Ice Layer Distributions in Firn Cores. Preprint. Ice sheets/Instrumentation. https://doi.org/10.5194/egusphere-2023-2351. 

Abstract An intermediate-depth (1751 m) ice core was drilled at the South Pole between 2014 and 2016 using the newly designed US Intermediate Depth Drill. The South Pole ice core is the highest-resolution interior East Antarctic ice core record that extends into the glacial period. The methods used at the South Pole to handle and log the drilled ice, the procedures used to safely retrograde the ice back to the National Science Foundation Ice Core Facility (NSF-ICF), and the methods used to process and sample the ice at the NSF-ICF are described. The South Pole ice core exhibited minimal brittle ice, which was likely due to site characteristics and, to a lesser extent, to drill technology and core handling procedures. 

Abstract A large volcanic sulfate increase observed in ice core records around 1450 C.E. has been attributed in previous studies to a volcanic eruption from the submarine Kuwae caldera in Vanuatu. Both EPMA–WDS (electron microprobe analysis using a wavelength dispersive spectrometer) and SEM–EDS (scanning electron microscopy analysis using an energy dispersive spectrometer) analyses of five microscopic volcanic ash (cryptotephra) particles extracted from the ice interval associated with a rise in sulfate ca. 1458 C.E. in the South Pole ice core (SPICEcore) indicate that the tephra deposits are chemically distinct from those erupted from the Kuwae caldera. Recognizing that the sulfate peak is not associated with the Kuwae volcano, and likely not a large stratospheric tropical eruption, requires revision of the stratospheric sulfate injection mass that is used for parameterization of paleoclimate models. Future work is needed to confirm that a volcanic eruption from Mt. Reclus is one of the possible sources of the 1458 C.E. sulfate anomaly in Antarctic ice cores. 

Abstract. The South Pole Ice Core (SPICEcore) was drilled in 2014–2016 to provide adetailed multi-proxy archive of paleoclimate conditions in East Antarcticaduring the Holocene and late Pleistocene. Interpretation of these recordsrequires an accurate depth–age relationship. Here, we present the SPICEcore (SP19) timescale for the age of the ice of SPICEcore. SP19 is synchronized to theWD2014 chronology from the West Antarctic Ice Sheet Divide (WAIS Divide) icecore using stratigraphic matching of 251 volcanic events. These eventsindicate an age of 54 302±519 BP (years before 1950) at thebottom of SPICEcore. Annual layers identified in sodium and magnesium ionsto 11 341 BP were used to interpolate between stratigraphic volcanic tiepoints, yielding an annually resolved chronology through the Holocene.Estimated timescale uncertainty during the Holocene is less than 18 yearsrelative to WD2014, with the exception of the interval between 1800 to 3100BP when uncertainty estimates reach ±25 years due to widely spacedvolcanic tie points. Prior to the Holocene, uncertainties remain within 124 years relative to WD2014. Results show an average Holocene accumulation rateof 7.4 cm yr−1 (water equivalent). The time variability of accumulation rateis consistent with expectations for steady-state ice flow through the modernspatial pattern of accumulation rate. Time variations in nitrateconcentration, nitrate seasonal amplitude and δ15N of N2 in turn are as expected for the accumulation rate variations. The highlyvariable yet well-constrained Holocene accumulation history at the site canhelp improve scientific understanding of deposition-sensitive climateproxies such as δ15N of N2 and photolyzed chemicalcompounds. 

Water-stable isotopes in polar ice cores are a widely used temperature proxy in paleoclimate reconstruction, yet calibration remains challenging in East Antarctica. Here, we reconstruct the magnitude and spatial pattern of Last Glacial Maximum surface cooling in Antarctica using borehole thermometry and firn properties in seven ice cores. West Antarctic sites cooled ~10°C relative to the preindustrial period. East Antarctic sites show a range from ~4° to ~7°C cooling, which is consistent with the results of global climate models when the effects of topographic changes indicated with ice core air-content data are included, but less than those indicated with the use of water-stable isotopes calibrated against modern spatial gradients. An altered Antarctic temperature inversion during the glacial reconciles our estimates with water-isotope observations.